麒麟菜多糖的研究——Ⅰ.琼枝多糖的性质及其红外光谱

STUDIES DN PQLYSACCHARIDE FRUM EUCHEUMA I.PROPDRTIES AND IR SPECTRA DF PQLYSACCHARIDE FROM EUCFEUMA CELARI NAE

  • 摘要: 琼枝多糖是琼枝(Eucheuma gclatinae)分离得到的一种硫酸酯化半乳聚糖。构成这种多糖的单糖主要是 D-半乳糖和3,6-脱水-D-半乳糖。分子量为 1.99×105,比旋光度为正值。大多数碱金属阳离子和碱土金属阳离子能使此多糖的胶凝能力提高。用碱或石灰处理时,琼枝多糖便部分脱去硫酸酿基团,3,6-脱水-D-半乳糖的含量增加。红外光谱分析证明,琼枝多糖在1240cm-1 、930cm-1和845cm-1有吸收峰。用氯化钾分级时,琼枝多糖可分为溶于氯化钾溶液和不溶于氯化钾溶液两个级分;前者的红外光谱除了同后者一样在 1240cm-1,930cm-1和845cm-1有吸收峰外,在 820cm-1处还有吸收峰。根据琼枝多糖的组成,性质和红外光谱,可以推断,溶于氯化钾溶液的级分是类 mu-卡拉胶;不溶于氯化钾溶液的级分是类 kappa—卡拉胶。

     

    Abstract: Euchexcnza gebcimiae is a red algae Hainan of China. A sulphated isolated from this algae. D-galactose and 3 6-anb.川ro-D--glactvse are Was mawr vent of this polysaccharide. The molecular weight was 1.99. Its specific was a positive value. compo- rotation The gelling ability of the polysaccharide increased due to tha presence ofmost of alkali metal ions and alkali-earth metal ions. Yhen the pvlysaccharida was treated with alkali or lime, the polysaccharide desulphste, and sulphate groups decreased and 3,6-and galactosa content increa- sed. fhe III spectra, of the polys.echaride showed absorption peaks at 1240 em-1, 930 cry and 845 em-1. Fractionation of the polysaccharide with potassium chloride eld pvtassiunz chlo- ridsoluble and insoluble fraction. IR spectra of soluole fraction showed absor Xioneak at 820 cm-' besides at 1244 cmr;, 930 em0I and 45 em.as insoluble fraction. According to the composition, properties and IR spectra of the polysaccharide, it was deduced that potassium chlorideJsvluble fraction is xnu-carrageenan-like, and in- soluble fraction is kappaKcarrageenan-like.

     

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