麒麟菜多糖的研究——Ⅱ 琼枝多糖溶液的流变性质

STUDIES ON THE POLYSACCHARIDE FROM EUSHEUMA——Ⅱ. RHEOLOGICAL PROPERTIES OF POLYSACCHARIDE SOLUTION FROM EUCHEUMA GELATINAE

  • 摘要: 本文研究了琼枝多糖溶液的流变性质,观察到琼枝多糖溶液其切变应力τ—切变速率 D,lgD—lgτ,D—η关系以及稠度指数和流动行为指数,在50℃—60℃温度间,出现突跃性的变化。按 Arrhenius方程式:η=Aev/RT,在lnη—1/T关系图中,30—50℃和60—80℃分成两条斜率不同的直线,说明在上述两个温度范围内,同一多糖溶液各具有不同的流动活化能,即在50℃—60℃之间溶液的流动活化能发生变化。琼枝多糖溶液由于稠度指数在50—60℃之间有突跃性下降,使得琼枝多糖在作为增稠剂或稳定剂时,使用温度应尽量避免超过50℃。琼枝多糖比海藻酸钠和具有水解度20%、分子量2.1×106 的部分水解聚丙烯酰胺,具有较高的增稠能力,是一种较好的增稠剂。

     

    Abstract: Studies on rheological properties of polysaccharide solution from Eucheuma gela-tinae were carried out. A sudden change on the relations of the the shear stress τ vsshear rate D, lgD vs lgτ, D vs η and the thickness index and flowing behavior indexof the polysaccharide solution was observed at temperature 50--60℃.It was found that the slope of the plot line of In n vs 1/τ based on the Arrheniusequation: n = A. e(v/RT) at the temperature ranges of 30--50℃ was differ from that of60--80℃. It was showed that the flowing activation energy at 30--50℃ was differentfrom 60--80℃, the change of flowing activation energy occurred at 50--60℃.Because of the soddenly reducing on the thickness index of the polysaccaridesolution at 50--60℃ as pointed out above, the application temperature over 50℃ mustbe avoided in using the polysaccharide as a thickner and stablizer.It was found that thickness of the polysaccharide was higher than sodium alginateand partial hydrolytic polyacrylamide (with a hydrolytic degree of 20% and a mole-cular weight of 2.1×105) and the polysaccharide from Eucheuma gelatinae was a goodthickener.

     

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